Chemists have been aware of the existence of coordination compounds con taining organic macrocyclic ligands since the first part of this century ; however, only during the past few years have they expanded research into the chemistry of these compounds. The expansion was initiated in the early 1960s by the synthesis and characterization of compounds containing some new macrocyclic ligands. The synthesis of compounds which may serve as model systems for some natural products containing large rings as ligands provided the main goal for the early expansion of research effort; indeed, a recurrent theme behind much of the reported chemistry has been the analogy between synthetic macrocyclic compounds and many natural-product systems. More recently, the emphases of reported research have ranged over the whole spectrum of chemistry, and the number of publications that discuss macrocyclic chemistry has increased at a dramatic rate. The completed research has been reported in a variety of journals throughout the world but there has been no previous attempt to bring the major developments together under one cover. This book, therefore, attempts to satisfy the need for a single source in which there is both a collection and a correlation of information concerning the coordination chemistry of macrocyclic compounds. The chapters in this book discuss various aspects of macrocyclic chemistry, and while these chapters as a whole constitute an in-depth survey of the state-of the-art of the field, each chapter is written as a complete unit.
Erscheinungsdatum: 12.10.2011

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Springer London, Limited

Plenum Press

United States, United States of America

Springer Nature, New York, NY, 2012

Boston, MA, 1979

New York, ©1979

Oct 12, 2011

sm21785524

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Front Matter....Pages i-xiv
General Introduction....Pages 1-16
Synthesis of Macrocyclic Complexes....Pages 17-144
Thermodynamics and Kinetics of Cation-Macrocycle Interaction....Pages 145-217
Structural Aspects....Pages 219-344
Ligand Field Spectra and Magnetic Properties of Synthetic Macrocyclic Complexes....Pages 345-392
Chemical Reactivity in Constrained Systems....Pages 393-460
Metal Complexes of Phthalocyanines....Pages 461-516
Coordination Chemistry of Porphyrins....Pages 517-536
Physicochemical Studies of Crown and Cryptate Complexes....Pages 537-602
Natural-Product Model Systems....Pages 603-654
Back Matter....Pages 655-664

1. General Introduction.- 1. Introductory Comments.- 2. General Comments.- 2.1. Definition of a Macrocyclic Compound.- 2.2. Historical Background.- 2.3. Abbreviations of Macrocyclic Compounds.- 2.4. Units.- 2.5. Chapter Layout.- References.- 2. Synthesis of Macrocyclic Complexes.- 1. Introduction.- 2. Tridentate Ligands.- 3. Tetradentate Ligands.- 3.1. N4 Donor Atoms.- 3.2. N2O2 Donor Atoms.- 3.3. N2S2 Donor Atoms.- 3.4. S4 Donor Atoms.- 3.5. P4 and P2S2 Donor Atoms.- 4. Pentadentate Ligands.- 5. Sexadentate Ligands.- 6. Binucleating Ligands.- 7. Clathrochelates.- 8. Conclusions.- References.-

2013-12-12